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Triisopropylphosphine
Chemical compound
Chemical compound
PiPr3 Pi-Pr3
Triisopropylphosphine is the tertiary phosphine with the formula P(CH(CH3)2)3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to Pi-Pr3 or PiPr3. This ligand is one of the most basic alkyl phosphines with a large ligand cone angle of 160.
Pi-Pr3 is similar to the more frequently used tricyclohexylphosphine. The triisopropyl derivative however, is a liquid at room temperature and more soluble in hydrocarbons.
References
References
- C. A. Tolman. (1977). "Steric Effects of Phosphorus Ligands in Organometallic Chemistry and Homogeneous Catalysis". [[Chem. Rev.]].
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