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Scandium dodecaboride


Scandium dodecaboride is a refractory metal boride.

Synthesis

ScB12 is formed by mixing a 7:1 ratio of boron powder and scandium oxide powder, heating to 2500 °C with a plasma torch or similar, quenching in cold water and washing with concentrated hydrochloric acid.

Crystallography

ScB12 was originally reported as having a cubic structure, later studies showed it to have tetragonal structure (unit cell with a=522pm, c=735pm). More recently it has been shown that there is indeed a cubic form but that it requires stabilization.

References

References

  1. Matkovich, V.I.. (1965). "The structure of metallic dodecaborides". Acta Crystallogr..
  2. Przybylska, Maria. (1963). "The Preparation and Structure of Lutetium Diboride, Scandium Dodecaboride and Lutetium Antimonide". J. Am. Chem. Soc..
  3. Paderno, Y.. (1995). "Stabilization of cubic scandium dodecaboride". Journal of Alloys and Compounds.
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