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Roche ester

Roche ester (methyl 3-hydroxy-2-methylpropionate) is a chemical compound with formula C5H10O3. It can exist as two enantiomers. Both are commercially available and have been widely used as starting blocks for the synthesis of many targets including dictyostatin, discodermolide and spongidepsin.

References

(2004). "Total Synthesis of (−)-Dictyostatin: Confirmation of Relative and Absolute Configurations". Wiley.
(2003). "The Development of a Practical Total Synthesis of Discodermolide, a Promising Microtubule-Stabilizing Anticancer Agent". Wiley.
(2006). "Total Synthesis of (−)-Spongidepsin". [[American Chemical Society]].

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methyl-esters

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