Phytoene

Structure

Phytoene is a symmetric molecule containing three conjugated double bonds. Phytoene has a UV-Vis absorption spectrum typical for a triply conjugated system with its main absorption maximum in the UVB range at 286 nm and with ε1% of 915.

Sources

Analysis of several fruits and vegetables showed that phytoene and phytofluene are found in majority of fruits and vegetables. In contrast to all other carotenoids, phytoene and phytofluene, the first carotenoid precursors in the biosynthetic pathway of other carotenoids, absorb light in the UV range.

History

The structure of phytoene was established and proven by total synthesis, by the Basil Weedon group in 1966.

References

References

1. "Carotenoid Biosynthesis".
2. [http://www.curehunter.com/public/keywordSummaryC073128-phytoene-synthase.do Phytoene synthase]
3. (November 2002). "Chemistry, Distribution, and Metabolism of Tomato Carotenoids and Their Impact on Human Health". Experimental Biology and Medicine.
4. Aust, W. Stahl, H. Sies, H. Tronnier, U. Heinrich. (2005). "Supplementation with tomato-based products increases lycopene, phytofluene, and phytoene levels in human serum and protects against UV-light-induced erythema". Int J Vitam Nutr Res.
5. (2006). "Anti-inflammatory effects of CoQ10 and colorless carotenoids". Journal of Cosmetic Dermatology.
6. Khachik, F., G.R. Beecher, M.B. Goli, and W.R. Lusby. (1991). "Separation, identifi cation, and quantification of carotenoids in fruits, vegetables and human plasma by high performance liquid chromatography". Pure Appl. Chem..
7. (1966). "Carotenoids and related compounds. XV. The structure and synthesis of phytoene, phytofluene, zeta-carotene, and neurosporene". J. Chem. Soc. C.