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Monocyclic monoterpene ketone monooxygenase

Class of enzymes

Class of enzymes

FieldValue
NameMonocyclic monoterpene ketone monooxygenase
EC_number1.14.13.105

Monocyclic monoterpene ketone monooxygenase (, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with systematic name (-)-menthone,NADPH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction

: (1) (-)-menthone + NADPH + H+ + O2 \rightleftharpoons (4R,7S)-7-isopropyl-4-methyloxepan-2-one + NADP+ + H2O : (2) dihydrocarvone + NADPH + H+ + O2 \rightleftharpoons 4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O : (3) (iso)-dihydrocarvone + NADPH + H+ + O2 \rightleftharpoons 6-isopropenyl-3-methyloxepan-2-one + NADP+ + H2O : (4a) 1-hydroxymenth-8-en-2-one + NADPH + H+ + O2 \rightleftharpoons 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O : (4b) 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one \rightleftharpoons 3-isopropenyl-6-oxoheptanoate (spontaneous)

Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD).

References

References

  1. (May 1999). "Rhodococcus erythropolis DCL14 contains a novel degradation pathway for limonene". Applied and Environmental Microbiology.
  2. (May 2000). "Purification and characterization of a Baeyer-Villiger mono-oxygenase from Rhodococcus erythropolis DCL14 involved in three different monocyclic monoterpene degradation pathways". The Biochemical Journal.
  3. (May 2000). "Metabolism of carveol and dihydrocarveol in Rhodococcus erythropolis DCL14". Microbiology.
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