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List of glues

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List of glues

Summary

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There are many adhesive substances that are considered or commonly referred to as glue. Historically, the term only referred to protein colloids prepared from animal flesh. The meaning has been extended to refer to any fluid adhesive.

Plant- and animal-based adhesives

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDateRoasted hydrocarbonsTar, pitch, and asphalt/ bitumenMixed-protein gluesCasein glueSoybean glueAlbumin glues (blood glues and egg albumin adhesive, EAA)Gelatin glueshide glue, including rabbit-skin glue;Keratin gluesHoof glue and horn glueFibrin glueWaxesBeeswaxStarch gluespotato starch, rice glue, wheatpasteDextrin gluesBritish gum, CoccoinaPolysaccharide gluesmucilage, agar, alginTree gums/resinsBalsam (fir) resins, such as Canada balsam, Dammar gum, Gum Arabic (also called acacia gum), MasticLatex rubber cementMethyl cellulose
Made from plants (especially wood) or fossil hydrocarbonsnatural or artificial destructive distillationHydrocarbon goo of no specific chemical formulaEmits Volatile organic compounds, especially when heatedhealth effects understudied (see Asphalt#Health and safety)dark, viscous, more flexible when heatedIndefinite, may stiffenIndefiniteReversibly becomes more flexible and fluid when heatedwater-repellant,Sealant, haftingprehistoric
Milk, limestone and brineMilk curd is mixed with alkalisnon-toxic (preservatives excepted)Once wet, 6–7 hours.~4 hours for softwood, 8 for hardwood; must be under pressure for 0.5-2 hrstensile strength exceeds most woods, 2,200-3,00 pounds per square inchwater-resistant, depending on alkalis usedWoodworking, paper glue, fireproof laminatesMedieval or earlier
As for casein glue, but using soy proteinSoy protein is mixed with alkalis
blood (serum albumin) or eggsprehistoric
Animal connective tissuehides are acid-treated, neutralized, and repeatedly soaked; the soaking-water is dried into chipshydrolyzed collagenUntil it coolsThermoplastic. Somewhat brittle when setWater-solubleCabinetmaking, bookbinding, lutherie, glue-size
hooves of ungulates, animal hornsHooves or horns are fragmented, boiled into goo, and acidifiedpartially- hydrolyzed keratinUntil it coolsThermoplastic. Hardens as it cools, but does not become brittleGluing and stiffening textiles, cabinetmaking, glass sealant
human fibrinogen and human thrombinwhen two parts are mixed, they form fibrin10–60 secondsconverts to fibrinMedicine
made by insects
starches (plant energy-storage chemicals)Starch may be purified before being mixed with water; leaving gluten in makes a more permanent bond
usually derived from potato starchmid-19th century
latex, a coagulating plant fluid, also made syntheticallylatex is dissolved in an organic solventorganic solvent evaporates as it setssolvent may be hazardous; latex is an allergen
cellulose, a plant structural material, and methyl chlorideheating cellulose with an alkali and reacting it with methyl chloride

[[Solvent]]-type glues

Main article: Plastic welding#Solvent welding

Solvent adhesives temporarily dissolve the substance they are gluing, and bond by solvent-welding material together with the re-solidified material.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDateKetonesAcetonePolystyrene cement/Butanone/methyl ethyl ketone (MEK)Dichloromethane
dissolves ABS plasticit is volatile
dissolves polystyreneit is volatileVapour is heavier-than-air and explosive. Toxic, neuropsychological effects. Rapidly absorbed through undamaged skin and lungs. Produces toxic ozone.
Dissolves:it is volatile, boiling at 39.6°C (103.3°F; 312.8K)Will also glue acrylic to wood. Clear, waterproof, exterior grades exist.24 hours to set fully.

Synthetic glues

Synthetic [[monomer]] glues

A tube of Super Glue cyanoacrylate
TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDateAcrylonitrileCyanoacrylate ("Superglue", "Krazy Glue")Methyl acrylate ("acrylic")
synthetic monomer
synthetic monomer
synthetic monomer

Synthetic [[polymer]] glues

Thermoplastic polymers

Main article: thermoplastic polymer, Hot-melt adhesive

Thermoplastic glues including hot-melt adhesives cure reversibly as they cool, like the gelatin and keratin glues listed above. They frequently don't emit volatiles unless overheated.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeSettingStrengthSolventsUsesDateEthylene-vinyl acetatePolyolefins(polyethylene, polypropylene, etc.)PolyamidesPolyestersPolyurethanesPolycaprolactone
syntheticpolyethylene mixed with about 11% vinyl acetate
syntheticthermosetting
synthetic
synthetic
synthetic
syntheticbiodegradablevery low melting temperature, 40 - and heat conductivity means it can be moulded by hand. Can be used to mould itself.
  • Styrene acrylic copolymer – e.g. "No More Nails"

Thermosetting polymers

Main article: thermosetting polymer

Thermosetting glues or thermosets cure irreversibly by polymerization. The polymerization can be triggered by heat or other radiation, or high pressure or a catalyst/hardener may be added.

TypeSubtypesSource(s)ManufactureChemistryVolatilesSafetyPropertiesShelf lifeWorking timeSettingStrengthSolventsUsesDatePhenol formaldehyde resins (PF), also called phenolic resinsResorcinol glue, Para tertiary butylphenol formaldehyde resinUrea-formaldehyde gluePolysulfides
syntheticresorcinol or similar is mixed with phenol to make a resin; cured by adding formaldehydeoffgasses phenol and formeldehydephenol and formeldehyde are toxic, PTBPF causes contact allergieslast=Boatfirst=Classicdate=2011-03-11title=Adhesives for Wooden Boats: Structural Gluesurl=https://www.classicboat.co.uk/practical-advice/adhesives-for-wooden-boats-structural-glues/access-date=2022-11-11website=Classic Boat Magazinelanguage=en-US}}A few years, unmixed.Temperature-dependent. Will not cure at temperatures below 10 C.Needs to be clampedStructuralWater-soluble until set, waterproof after.laminating plywood, especially for exterior use; woodworking
syntheticurea and formaldehydeoffgasses urea and formeldehydeformeldehyde is toxic, urea is an irritantthermosetting
syntheticWill melt acrylic, polycarbonate, ABS and PVC plastic. Can be used to glue nylon, epoxy, and polyoxymethylene.
  • Epoxy resins
    • Epoxy putty
  • Polyvinyls
    • Polyvinyl acetate (PVA) Includes white glue (e.g. Elmer's Glue) and yellow carpenter's glue (Aliphatic resin) (Brands include Titebond and Lepage)
    • Polyvinyl alcohol
    • Polyvinyl chloride (PVC)
    • Polyvinyl chloride emulsion (PVCE) – a water-miscible emulsion that polymerizes as it cures
    • Polyvinylpyrrolidone (component of glue sticks)
  • Silicone resins
  • Silyl modified polymers

By use

  • Postage stamp gum may be a mixture of assorted starch and resin adhesives
  • Library paste is usually starch-based
  • Meat glue is a variety of culinary binding agents

References

es:Pegamento nl:Lijst van lijmsoorten pt:Cola (desambiguação)

References

  1. (1990). "Handbook of Adhesives".
  2. Simon B.N. Thompson. (Winter 2010). "Implications for cognitive rehabilitation and brain injury from exposure to Methyl Ethyl Ketone (MEK): a review". Journal of Cognitive Rehabilitation.
  3. "Tensol 70 Glue {{!}} EVO-STIK Two Part Adhesive {{!}} Silmid".
  4. "Chemical Bonding {{!}} Perspex Fabrication {{!}} UV & Solvent bonding, Tensol 70".
  5. "Gluing Acrylic {{!}} Acrylic".
  6. Boat, Classic. (2011-03-11). "Adhesives for Wooden Boats: Structural Glues".
  7. "Marine Caulking & Adhesives".
  8. "Art & Architecture Thesaurus Full Record Display (Getty Research)".
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