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List of glues
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There are many adhesive substances that are considered or commonly referred to as glue. Historically, the term only referred to protein colloids prepared from animal flesh. The meaning has been extended to refer to any fluid adhesive.
Plant- and animal-based adhesives
| Type | Subtypes | Source(s) | Manufacture | Chemistry | Volatiles | Safety | Properties | Shelf life | Working time | Setting | Strength | Solvents | Uses | Date | Roasted hydrocarbons | Tar, pitch, and asphalt/ bitumen | Mixed-protein glues | Casein glue | Soybean glue | Albumin glues (blood glues and egg albumin adhesive, EAA) | Gelatin glues | hide glue, including rabbit-skin glue; | Keratin glues | Hoof glue and horn glue | Fibrin glue | Waxes | Beeswax | Starch glues | potato starch, rice glue, wheatpaste | Dextrin glues | British gum, Coccoina | Polysaccharide glues | mucilage, agar, algin | Tree gums/resins | Balsam (fir) resins, such as Canada balsam, Dammar gum, Gum Arabic (also called acacia gum), Mastic | Latex rubber cement | Methyl cellulose |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Made from plants (especially wood) or fossil hydrocarbons | natural or artificial destructive distillation | Hydrocarbon goo of no specific chemical formula | Emits Volatile organic compounds, especially when heated | health effects understudied (see Asphalt#Health and safety) | dark, viscous, more flexible when heated | Indefinite, may stiffen | Indefinite | Reversibly becomes more flexible and fluid when heated | water-repellant, | Sealant, hafting | prehistoric | ||||||||||||||||||||||||||
| Milk, limestone and brine | Milk curd is mixed with alkalis | non-toxic (preservatives excepted) | Once wet, 6–7 hours. | ~4 hours for softwood, 8 for hardwood; must be under pressure for 0.5-2 hrs | tensile strength exceeds most woods, 2,200-3,00 pounds per square inch | water-resistant, depending on alkalis used | Woodworking, paper glue, fireproof laminates | Medieval or earlier | |||||||||||||||||||||||||||||
| As for casein glue, but using soy protein | Soy protein is mixed with alkalis | ||||||||||||||||||||||||||||||||||||
| blood (serum albumin) or eggs | prehistoric | ||||||||||||||||||||||||||||||||||||
| Animal connective tissue | hides are acid-treated, neutralized, and repeatedly soaked; the soaking-water is dried into chips | hydrolyzed collagen | Until it cools | Thermoplastic. Somewhat brittle when set | Water-soluble | Cabinetmaking, bookbinding, lutherie, glue-size | |||||||||||||||||||||||||||||||
| hooves of ungulates, animal horns | Hooves or horns are fragmented, boiled into goo, and acidified | partially- hydrolyzed keratin | Until it cools | Thermoplastic. Hardens as it cools, but does not become brittle | Gluing and stiffening textiles, cabinetmaking, glass sealant | ||||||||||||||||||||||||||||||||
| human fibrinogen and human thrombin | when two parts are mixed, they form fibrin | 10–60 seconds | converts to fibrin | Medicine | |||||||||||||||||||||||||||||||||
| made by insects | |||||||||||||||||||||||||||||||||||||
| starches (plant energy-storage chemicals) | Starch may be purified before being mixed with water; leaving gluten in makes a more permanent bond | ||||||||||||||||||||||||||||||||||||
| usually derived from potato starch | mid-19th century | ||||||||||||||||||||||||||||||||||||
| latex, a coagulating plant fluid, also made synthetically | latex is dissolved in an organic solvent | organic solvent evaporates as it sets | solvent may be hazardous; latex is an allergen | ||||||||||||||||||||||||||||||||||
| cellulose, a plant structural material, and methyl chloride | heating cellulose with an alkali and reacting it with methyl chloride |
[[Solvent]]-type glues
Main article: Plastic welding#Solvent welding
Solvent adhesives temporarily dissolve the substance they are gluing, and bond by solvent-welding material together with the re-solidified material.
| Type | Subtypes | Source(s) | Manufacture | Chemistry | Volatiles | Safety | Properties | Shelf life | Working time | Setting | Strength | Solvents | Uses | Date | Ketones | Acetone | Polystyrene cement/Butanone/methyl ethyl ketone (MEK) | Dichloromethane |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| dissolves ABS plastic | it is volatile | |||||||||||||||||
| dissolves polystyrene | it is volatile | Vapour is heavier-than-air and explosive. Toxic, neuropsychological effects. Rapidly absorbed through undamaged skin and lungs. Produces toxic ozone. | ||||||||||||||||
| Dissolves: | it is volatile, boiling at 39.6°C (103.3°F; 312.8K) | Will also glue acrylic to wood. Clear, waterproof, exterior grades exist. | 24 hours to set fully. |
Synthetic glues
Synthetic [[monomer]] glues

| Type | Subtypes | Source(s) | Manufacture | Chemistry | Volatiles | Safety | Properties | Shelf life | Working time | Setting | Strength | Solvents | Uses | Date | Acrylonitrile | Cyanoacrylate ("Superglue", "Krazy Glue") | Methyl acrylate ("acrylic") |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| synthetic monomer | |||||||||||||||||
| synthetic monomer | |||||||||||||||||
| synthetic monomer |
Synthetic [[polymer]] glues
Thermoplastic polymers
Main article: thermoplastic polymer, Hot-melt adhesive
Thermoplastic glues including hot-melt adhesives cure reversibly as they cool, like the gelatin and keratin glues listed above. They frequently don't emit volatiles unless overheated.
| Type | Subtypes | Source(s) | Manufacture | Chemistry | Volatiles | Safety | Properties | Shelf life | Setting | Strength | Solvents | Uses | Date | Ethylene-vinyl acetate | Polyolefins | (polyethylene, polypropylene, etc.) | Polyamides | Polyesters | Polyurethanes | Polycaprolactone |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| synthetic | polyethylene mixed with about 11% vinyl acetate | |||||||||||||||||||
| synthetic | thermosetting | |||||||||||||||||||
| synthetic | ||||||||||||||||||||
| synthetic | ||||||||||||||||||||
| synthetic | ||||||||||||||||||||
| synthetic | biodegradable | very low melting temperature, 40 - and heat conductivity means it can be moulded by hand. Can be used to mould itself. |
- Styrene acrylic copolymer – e.g. "No More Nails"
Thermosetting polymers
Main article: thermosetting polymer
Thermosetting glues or thermosets cure irreversibly by polymerization. The polymerization can be triggered by heat or other radiation, or high pressure or a catalyst/hardener may be added.
| Type | Subtypes | Source(s) | Manufacture | Chemistry | Volatiles | Safety | Properties | Shelf life | Working time | Setting | Strength | Solvents | Uses | Date | Phenol formaldehyde resins (PF), also called phenolic resins | Resorcinol glue, Para tertiary butylphenol formaldehyde resin | Urea-formaldehyde glue | Polysulfides | |||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| synthetic | resorcinol or similar is mixed with phenol to make a resin; cured by adding formaldehyde | offgasses phenol and formeldehyde | phenol and formeldehyde are toxic, PTBPF causes contact allergies | last=Boat | first=Classic | date=2011-03-11 | title=Adhesives for Wooden Boats: Structural Glues | url=https://www.classicboat.co.uk/practical-advice/adhesives-for-wooden-boats-structural-glues/ | access-date=2022-11-11 | website=Classic Boat Magazine | language=en-US}} | A few years, unmixed. | Temperature-dependent. Will not cure at temperatures below 10 C. | Needs to be clamped | Structural | Water-soluble until set, waterproof after. | laminating plywood, especially for exterior use; woodworking | ||||||||
| synthetic | urea and formaldehyde | offgasses urea and formeldehyde | formeldehyde is toxic, urea is an irritant | thermosetting | |||||||||||||||||||||
| synthetic | Will melt acrylic, polycarbonate, ABS and PVC plastic. Can be used to glue nylon, epoxy, and polyoxymethylene. |
- Epoxy resins
- Epoxy putty
- Polyvinyls
- Polyvinyl acetate (PVA) Includes white glue (e.g. Elmer's Glue) and yellow carpenter's glue (Aliphatic resin) (Brands include Titebond and Lepage)
- Polyvinyl alcohol
- Polyvinyl chloride (PVC)
- Polyvinyl chloride emulsion (PVCE) – a water-miscible emulsion that polymerizes as it cures
- Polyvinylpyrrolidone (component of glue sticks)
- Silicone resins
- Silyl modified polymers
By use
- Postage stamp gum may be a mixture of assorted starch and resin adhesives
- Library paste is usually starch-based
- Meat glue is a variety of culinary binding agents
References
es:Pegamento nl:Lijst van lijmsoorten pt:Cola (desambiguação)
References
- (1990). "Handbook of Adhesives".
- Simon B.N. Thompson. (Winter 2010). "Implications for cognitive rehabilitation and brain injury from exposure to Methyl Ethyl Ketone (MEK): a review". Journal of Cognitive Rehabilitation.
- "Tensol 70 Glue {{!}} EVO-STIK Two Part Adhesive {{!}} Silmid".
- "Chemical Bonding {{!}} Perspex Fabrication {{!}} UV & Solvent bonding, Tensol 70".
- "Gluing Acrylic {{!}} Acrylic".
- Boat, Classic. (2011-03-11). "Adhesives for Wooden Boats: Structural Glues".
- "Marine Caulking & Adhesives".
- "Art & Architecture Thesaurus Full Record Display (Getty Research)".
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