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Isotopes of phosphorus
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Although phosphorus (15P) has 22 known isotopes from 26P to 47P; only 31P is stable, thus phosphorus is considered a monoisotopic element. The longest-lived radioactive isotopes are 33P with a half-life of 25.35 days and 32P with a half-life of 14.269 days. All others have half-lives of under 2.5 minutes, most under a second.
List of isotopes
Phosphorus-24
|-id=Phosphorus-26 | β+ (62.9%)
| 26Si |
|---|
| β+, p (35.1%) |
| 25Al |
| - |
| β+, 2p (1.99%) |
| 24Mg |
| -id=Phosphorus-26m |
| 115(8) ns |
| IT |
| 26P |
| (1+) |
| |-id=Phosphorus-27 | β+ (99.93%)
| 27Si |
|---|
| β+, p (0.07%) |
| 26Al |
| -id=Phosphorus-28 |
| β+ |
| 28Si |
| - |
| β+, p (.0013%) |
| 27Al |
| - |
| β+, α (8.6×10−4%) |
| 24Mg |
| -id=Phosphorus-29 |
| 29P |
| 28.98180037(39) |
| 4.102(4) s |
| β+ |
| 29Si |
| 1/2+ |
| |-id=Phosphorus-30 | 30P | 29.978313490(69) | 2.5000(17) min | β+ | 30Si | 1+ | |-id=Phosphorus-31 | 31P | 30.97376199768(80) | 1/2+
| 1.0000 |
|---|
| 32P |
| 31.973907643(42) |
| 14.269(7) d |
| β− |
| 32S |
| 1+ |
| Trace |
| - |
| 33P |
| 32.9717257(12) |
| 25.35(11) d |
| β− |
| 33S |
| 1/2+ |
| |-id=Phosphorus-34 | 34P | 33.97364589(87) | 12.43(10) s | β− | 34S | 1+ | |-id=Phosphorus-35 | 35P | 34.9733140(20) | 47.3(8) s | β− | 35S | 1/2+ | |-id=Phosphorus-36 | β−
| 36S |
|---|
| β−, n? |
| 35S |
| -id=Phosphorus-37 |
| β− |
| 37S |
| - |
| β−, n? |
| 36S |
| -id=Phosphorus-38 |
| β− (88%) |
| 38S |
| - |
| β−, n (12%) |
| 37S |
| -id=Phosphorus-39 |
| β− (74%) |
| 39S |
| - |
| β−, n (26%) |
| 38S |
| -id=Phosphorus-40 |
| β− (84.2%) |
| 40S |
| - |
| β−, n (15.8%) |
| 39S |
| - |
| β−, 2n? |
| 38S |
| -id=Phosphorus-41 |
| β− (70%) |
| 41S |
| - |
| β−, n (30%) |
| 40S |
| - |
| β−, 2n? |
| 39S |
| -id=Phosphorus-42 |
| β− (50%) |
| 42S |
| - |
| β−, n (50%) |
| 41S |
| - |
| β−, 2n? |
| 40S |
| -id=Phosphorus-43 |
| β−, n |
| 42S |
| - |
| β−, 2n ? |
| 41S |
| -id=Phosphorus-44 |
| β−, n (55%) |
| 43S |
| - |
| β− (24%) |
| 44S |
| - |
| β−, 2n (21%) |
| 42S |
| -id=Phosphorus-45 |
| β−, n (79%) |
| 44S |
| - |
| β−, 2n (21%) |
| 43S |
| -id=Phosphorus-46 |
| [200 ns] |
| β−? |
| 46S |
| - |
| β−, n? |
| 45S |
| - |
| β−, 2n? |
| 44S |
| -id=Phosphorus-47 |
| [400 ns] |
| β− |
| 47S |
| - |
| β−, n? |
| 46S |
| - |
| β−, 2n? |
| 45S |
Radioactive isotopes
Phosphorus-32
Main article: Phosphorus-32}}32P is a radioactive isotope of phosphorus with relative atomic mass 31.973907 and half-life of 14.26 days. 32P is a radioactive isotope of phosphorus with beta particle-emitting radiocytotoxic activity. Emitted by 32P, beta particles directly damage cellular DNA and, by ionizing intracellular water to produce several types of cytotoxic free radicals and superoxides, indirectly damage intracellular biological macromolecules, resulting in tumor cell death.{{Cite web
Phosphorus-33
33P is an artificial radioactive element produced with a low yield by the neutron bombardment of 31P (stable). It is a pure β-emitter, like 32P, and can be used as an alternative to it in research in molecular biology. Indeed, its longer life time and especially its smaller decay energy make its manipulation simpler in the laboratory. In the medical field, 33P has been used in the treatment of arterial stenosis but is no longer indicated at this time.
References
References
- (1 December 2025). "Precision Mass Measurement of 26 P and 27 S and Their Impact on the 26 P( p , γ ) 27 S Reaction in Stellar X-Ray Bursts". The Astrophysical Journal.
- (2022). "Crossing ''N'' {{=}} 28 toward the neutron drip line: first measurement of half-lives at FRIB". Physical Review Letters.
- "Phosphorus-32".
- "Phosphorus 33 (P-33)".
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