Isochoric process

Formalism

An isochoric thermodynamic quasi-static process is characterized by constant volume, i.e., . The process does no pressure-volume work, since such work is defined by W = P \Delta V , where P is pressure. The sign convention is such that positive work is performed by the system on the environment.

If the process is not quasi-static, the work can perhaps be done in a volume constant thermodynamic process.

For a reversible process, the first law of thermodynamics gives the change in the system's internal energy: dU = dQ - dW

Replacing work with a change in volume gives dU = dQ - P , dV

Since the process is isochoric, , the previous equation now gives dU = dQ

Using the definition of specific heat capacity at constant volume, , where m is the mass of the gas, we get dQ = m c_\mathrm{v} , dT

Integrating both sides yields \Delta Q\ = m \int_{T_1}^{T_2} ! c_\mathrm{v} , dT, where cv is the specific heat capacity at constant volume, T1 is the initial temperature and T2 is the final temperature. We conclude with: \Delta Q\ = m c_\mathrm{v} \Delta T

On a pressure volume diagram, an isochoric process appears as a straight vertical line. Its thermodynamic conjugate, an isobaric process would appear as a straight horizontal line.

Ideal gas

If an ideal gas is used in an isochoric process, and the quantity of gas stays constant, then the increase in energy is proportional to an increase in temperature and pressure. For example a gas heated in a rigid container: the pressure and temperature of the gas will increase, but the volume will remain the same.

Ideal Otto cycle

The ideal Otto cycle is an example of an isochoric process when it is assumed that the burning of the gasoline-air mixture in an internal combustion engine car is instantaneous. There is an increase in the temperature and the pressure of the gas inside the cylinder while the volume remains the same.

Etymology

The noun "isochor" and the adjective "isochoric" are derived from the Greek words ἴσος (isos) meaning "equal", and χῶρος (khôros) meaning "space."

References

References

1. Ansermet, J.-P., Brechet, S.D. (2019). ''Principles of Thermodynamics'', Cambridge University Press, Cambridge UK, p. 113.