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Germacrene A alcohol dehydrogenase

Field	Value
Name	Germacrene A alcohol dehydrogenase
EC_number	1.1.1.314

Germacrene A alcohol dehydrogenase () is an enzyme with systematic name germacra-1(10),4,11(13)-trien-12-ol:NADP+ oxidoreductase. This enzyme catalyses the following chemical reaction

: germacra-1(10),4,11(13)-trien-12-ol + 2 NADP+ + H2O \rightleftharpoons germacra-1(10),4,11(13)-trien-12-oate + 2 NADPH + 3 H+ (overall reaction) : (1a) germacra-1(10),4,11(13)-trien-12-ol + NADP+ \rightleftharpoons germacra-1(10),4,11(13)-trien-12-al + NADPH + H+ : (1b) germacra-1(10),4,11(13)-trien-12-al + NADP+ + H2O \rightleftharpoons germacra-1(10),4,11(13)-trien-12-oate + NADPH + 2 H+

In Lactuca sativa this enzyme is a multifunctional enzyme with EC 1.14.13.123.

References

(April 2001). "Biosynthesis of germacrene A carboxylic acid in chicory roots. Demonstration of a cytochrome P450 (+)-germacrene a hydroxylase and NADP+-dependent sesquiterpenoid dehydrogenase(s) involved in sesquiterpene lactone biosynthesis". Plant Physiology.
(May 2010). "Biochemical conservation and evolution of germacrene A oxidase in asteraceae". The Journal of Biological Chemistry.

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ec-1.1.1

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