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Electron configurations of the elements (data page)

Chemical data page


Chemical data page

This page shows the electron configurations of the neutral gaseous atoms in their ground states. For each atom the subshells are given first in concise form, then with all subshells written out, followed by the number of electrons per shell. For phosphorus (element 15) as an example, the concise form is [Ne] 3s2 3p3. Here [Ne] refers to the core electrons which are the same as for the element neon (Ne), the last noble gas before phosphorus in the periodic table. The valence electrons (here 3s2 3p3) are written explicitly for all atoms.

Electron configurations of elements beyond hassium (element 108) have never been measured; predictions are used below. NOTOC As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration , written as , but whose actual configuration given in the table below is .

Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments. In many cases, multiple configurations are within a small range of energies and the irregularities shown below do not necessarily have a clear relation to chemical behaviour. For the undiscovered eighth-row elements, mixing of configurations is expected to be very important, and sometimes the result can no longer be well-described by a single configuration.

Legend1 H hydrogen : 1s1noble gas}}2 He helium : 1s23 Li lithium : [He] 2s14 Be beryllium : [He] 2s25 B boron : [He] 2s2 2p16 C carbon : [He] 2s2 2p27 N nitrogen : [He] 2s2 2p38 O oxygen : [He] 2s2 2p49 F fluorine : [He] 2s2 2p5noble gas}}10 Ne neon : [He] 2s2 2p611 Na sodium : [Ne] 3s112 Mg magnesium : [Ne] 3s213 Al aluminium : [Ne] 3s2 3p114 Si silicon : [Ne] 3s2 3p215 P phosphorus : [Ne] 3s2 3p316 S sulfur : [Ne] 3s2 3p417 Cl chlorine : [Ne] 3s2 3p5noble gas}}18 Ar argon : [Ne] 3s2 3p619 K potassium : [Ar] 4s120 Ca calcium : [Ar] 4s221 Sc scandium : [Ar] 3d1 4s222 Ti titanium : [Ar] 3d2 4s223 V vanadium : [Ar] 3d3 4s224 Cr chromium : [Ar] 3d5 4s125 Mn manganese : [Ar] 3d5 4s226 Fe iron : [Ar] 3d6 4s227 Co cobalt : [Ar] 3d7 4s228 Ni nickel : [Ar] 3d8 4s229 Cu copper : [Ar] 3d10 4s130 Zn zinc : [Ar] 3d10 4s231 Ga gallium : [Ar] 3d10 4s2 4p132 Ge germanium : [Ar] 3d10 4s2 4p233 As arsenic : [Ar] 3d10 4s2 4p334 Se selenium : [Ar] 3d10 4s2 4p435 Br bromine : [Ar] 3d10 4s2 4p5noble gas}}36 Kr krypton : [Ar] 3d10 4s2 4p637 Rb rubidium : [Kr] 5s138 Sr strontium : [Kr] 5s239 Y yttrium : [Kr] 4d1 5s240 Zr zirconium : [Kr] 4d2 5s241 Nb niobium : [Kr] 4d4 5s142 Mo molybdenum : [Kr] 4d5 5s143 Tc technetium : [Kr] 4d5 5s244 Ru ruthenium : [Kr] 4d7 5s145 Rh rhodium : [Kr] 4d8 5s146 Pd palladium : [Kr] 4d1047 Ag silver : [Kr] 4d10 5s148 Cd cadmium : [Kr] 4d10 5s249 In indium : [Kr] 4d10 5s2 5p150 Sn tin : [Kr] 4d10 5s2 5p251 Sb antimony : [Kr] 4d10 5s2 5p352 Te tellurium : [Kr] 4d10 5s2 5p453 I iodine : [Kr] 4d10 5s2 5p5noble gas}}54 Xe xenon : [Kr] 4d10 5s2 5p655 Cs caesium : [Xe] 6s156 Ba barium : [Xe] 6s257 La lanthanum : [Xe] 5d1 6s258 Ce cerium : [Xe] 4f1 5d1 6s259 Pr praseodymium : [Xe] 4f3 6s260 Nd neodymium : [Xe] 4f4 6s261 Pm promethium : [Xe] 4f5 6s262 Sm samarium : [Xe] 4f6 6s263 Eu europium : [Xe] 4f7 6s264 Gd gadolinium : [Xe] 4f7 5d1 6s265 Tb terbium : [Xe] 4f9 6s266 Dy dysprosium : [Xe] 4f10 6s267 Ho holmium : [Xe] 4f11 6s268 Er erbium : [Xe] 4f12 6s269 Tm thulium : [Xe] 4f13 6s270 Yb ytterbium : [Xe] 4f14 6s271 Lu lutetium : [Xe] 4f14 5d1 6s272 Hf hafnium : [Xe] 4f14 5d2 6s273 Ta tantalum : [Xe] 4f14 5d3 6s274 W tungsten : [Xe] 4f14 5d4 6s275 Re rhenium : [Xe] 4f14 5d5 6s276 Os osmium : [Xe] 4f14 5d6 6s277 Ir iridium : [Xe] 4f14 5d7 6s278 Pt platinum : [Xe] 4f14 5d9 6s179 Au gold : [Xe] 4f14 5d10 6s180 Hg mercury : [Xe] 4f14 5d10 6s281 Tl thallium : [Xe] 4f14 5d10 6s2 6p182 Pb lead : [Xe] 4f14 5d10 6s2 6p283 Bi bismuth : [Xe] 4f14 5d10 6s2 6p384 Po polonium : [Xe] 4f14 5d10 6s2 6p485 At astatine : [Xe] 4f14 5d10 6s2 6p5noble gas}}86 Rn radon : [Xe] 4f14 5d10 6s2 6p687 Fr francium : [Rn] 7s188 Ra radium : [Rn] 7s289 Ac actinium : [Rn] 6d1 7s290 Th thorium : [Rn] 6d2 7s291 Pa protactinium : [Rn] 5f2 6d1 7s292 U uranium : [Rn] 5f3 6d1 7s293 Np neptunium : [Rn] 5f4 6d1 7s294 Pu plutonium : [Rn] 5f6 7s295 Am americium : [Rn] 5f7 7s296 Cm curium : [Rn] 5f7 6d1 7s297 Bk berkelium : [Rn] 5f9 7s298 Cf californium : [Rn] 5f10 7s299 Es einsteinium : [Rn] 5f11 7s2100 Fm fermium : [Rn] 5f12 7s2101 Md mendelevium : [Rn] 5f13 7s2102 No nobelium : [Rn] 5f14 7s2103 Lr lawrencium : [Rn] 5f14 7s2 7p1104 Rf rutherfordium : [Rn] 5f14 6d2 7s2105 Db dubnium : [Rn] 5f14 6d3 7s2106 Sg seaborgium : [Rn] 5f14 6d4 7s2107 Bh bohrium : [Rn] 5f14 6d5 7s2108 Hs hassium : [Rn] 5f14 6d6 7s2109 Mt meitnerium : [Rn] 5f14 6d7 7s2 (predicted)110 Ds darmstadtium : [Rn] 5f14 6d8 7s2 (predicted)111 Rg roentgenium : [Rn] 5f14 6d9 7s2 (predicted)112 Cn copernicium : [Rn] 5f14 6d10 7s2 (predicted)113 Nh nihonium : [Rn] 5f14 6d10 7s2 7p1 (predicted)114 Fl flerovium : [Rn] 5f14 6d10 7s2 7p2 (predicted)115 Mc moscovium : [Rn] 5f14 6d10 7s2 7p3 (predicted)116 Lv livermorium : [Rn] 5f14 6d10 7s2 7p4 (predicted)117 Ts tennessine : [Rn] 5f14 6d10 7s2 7p5 (predicted)noble gas}}118 Og oganesson : [Rn] 5f14 6d10 7s2 7p6 (predicted)
1s2s2p3s3p3d4s4p4d4f5s5p5d5f6s6p6d7s7p
1s1
1
1s2
2
1s22s1
21
1s22s2
22
1s22s22p1
23
1s22s22p2
24
1s22s22p3
25
1s22s22p4
26
1s22s22p5
27
1s22s22p6
28
1s22s22p63s1
281
1s22s22p63s2
282
1s22s22p63s23p1
283
1s22s22p63s23p2
284
1s22s22p63s23p3
285
1s22s22p63s23p4
286
1s22s22p63s23p5
287
1s22s22p63s23p6
288
1s22s22p63s23p64s1
2881
1s22s22p63s23p64s2
2882
1s22s22p63s23p63d14s2
2892
1s22s22p63s23p63d24s2
28102
1s22s22p63s23p63d34s2
28112
1s22s22p63s23p63d54s1
28131
1s22s22p63s23p63d54s2
28132
1s22s22p63s23p63d64s2
28142
1s22s22p63s23p63d74s2
28152
1s22s22p63s23p63d84s2
28162
1s22s22p63s23p63d104s1
28181
1s22s22p63s23p63d104s2
28182
1s22s22p63s23p63d104s24p1
28183
1s22s22p63s23p63d104s24p2
28184
1s22s22p63s23p63d104s24p3
28185
1s22s22p63s23p63d104s24p4
28186
1s22s22p63s23p63d104s24p5
28187
1s22s22p63s23p63d104s24p6
28188
1s22s22p63s23p63d104s24p65s1
281881
1s22s22p63s23p63d104s24p65s2
281882
1s22s22p63s23p63d104s24p64d15s2
281892
1s22s22p63s23p63d104s24p64d25s2
2818102
1s22s22p63s23p63d104s24p64d45s1
2818121
1s22s22p63s23p63d104s24p64d55s1
2818131
1s22s22p63s23p63d104s24p64d55s2
2818132
1s22s22p63s23p63d104s24p64d75s1
2818151
1s22s22p63s23p63d104s24p64d85s1
2818161
1s22s22p63s23p63d104s24p64d10
281818
1s22s22p63s23p63d104s24p64d105s1
2818181
1s22s22p63s23p63d104s24p64d105s2
2818182
1s22s22p63s23p63d104s24p64d105s25p1
2818183
1s22s22p63s23p63d104s24p64d105s25p2
2818184
1s22s22p63s23p63d104s24p64d105s25p3
2818185
1s22s22p63s23p63d104s24p64d105s25p4
2818186
1s22s22p63s23p63d104s24p64d105s25p5
2818187
1s22s22p63s23p63d104s24p64d105s25p6
2818188
1s22s22p63s23p63d104s24p64d105s25p66s1
28181881
1s22s22p63s23p63d104s24p64d105s25p66s2
28181882
1s22s22p63s23p63d104s24p64d105s25p65d16s2
28181892
1s22s22p63s23p63d104s24p64d104f15s25p65d16s2
28181992
1s22s22p63s23p63d104s24p64d104f35s25p66s2
28182182
1s22s22p63s23p63d104s24p64d104f45s25p66s2
28182282
1s22s22p63s23p63d104s24p64d104f55s25p66s2
28182382
1s22s22p63s23p63d104s24p64d104f65s25p66s2
28182482
1s22s22p63s23p63d104s24p64d104f75s25p66s2
28182582
1s22s22p63s23p63d104s24p64d104f75s25p65d16s2
28182592
1s22s22p63s23p63d104s24p64d104f95s25p66s2
28182782
1s22s22p63s23p63d104s24p64d104f105s25p66s2
28182882
1s22s22p63s23p63d104s24p64d104f115s25p66s2
28182982
1s22s22p63s23p63d104s24p64d104f125s25p66s2
28183082
1s22s22p63s23p63d104s24p64d104f135s25p66s2
28183182
1s22s22p63s23p63d104s24p64d104f145s25p66s2
28183282
1s22s22p63s23p63d104s24p64d104f145s25p65d16s2
28183292
1s22s22p63s23p63d104s24p64d104f145s25p65d26s2
281832102
1s22s22p63s23p63d104s24p64d104f145s25p65d36s2
281832112
1s22s22p63s23p63d104s24p64d104f145s25p65d46s2
281832122
1s22s22p63s23p63d104s24p64d104f145s25p65d56s2
281832132
1s22s22p63s23p63d104s24p64d104f145s25p65d66s2
281832142
1s22s22p63s23p63d104s24p64d104f145s25p65d76s2
281832152
1s22s22p63s23p63d104s24p64d104f145s25p65d96s1
281832171
1s22s22p63s23p63d104s24p64d104f145s25p65d106s1
281832181
1s22s22p63s23p63d104s24p64d104f145s25p65d106s2
281832182
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p1
281832183
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p2
281832184
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p3
281832185
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p4
281832186
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p5
281832187
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p6
281832188
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p67s1
2818321881
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p67s2
2818321882
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p66d17s2
2818321892
1s22s22p63s23p63d104s24p64d104f145s25p65d106s26p66d27s2
28183218102
1s22s22p63s23p63d104s24p64d104f145s25p65d105f26s26p66d17s2
2818322092
1s22s22p63s23p63d104s24p64d104f145s25p65d105f36s26p66d17s2
2818322192
1s22s22p63s23p63d104s24p64d104f145s25p65d105f46s26p66d17s2
2818322292
1s22s22p63s23p63d104s24p64d104f145s25p65d105f66s26p67s2
2818322482
1s22s22p63s23p63d104s24p64d104f145s25p65d105f76s26p67s2
2818322582
1s22s22p63s23p63d104s24p64d104f145s25p65d105f76s26p66d17s2
2818322592
1s22s22p63s23p63d104s24p64d104f145s25p65d105f96s26p67s2
2818322782
1s22s22p63s23p63d104s24p64d104f145s25p65d105f106s26p67s2
2818322882
1s22s22p63s23p63d104s24p64d104f145s25p65d105f116s26p67s2
2818322982
1s22s22p63s23p63d104s24p64d104f145s25p65d105f126s26p67s2
2818323082
1s22s22p63s23p63d104s24p64d104f145s25p65d105f136s26p67s2
2818323182
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p67s2
2818323282
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p67s27p1
2818323283
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d27s2
28183232102
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d37s2
28183232112
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d47s2
28183232122
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d57s2
28183232132
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d67s2
28183232142
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d77s2
28183232152
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d87s2
28183232162
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d97s2
28183232172
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s2
28183232182
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p1
28183232183
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p2
28183232184
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p3
28183232185
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p4
28183232186
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p5
28183232187
1s22s22p63s23p63d104s24p64d104f145s25p65d105f146s26p66d107s27p6
28183232188

:

References

All sources concur with the data above except in the instances listed separately:

NIST

  • http://physics.nist.gov/PhysRefData/IonEnergy/ionEnergy.html ; retrieved July 2005, (elements 1–104) based on:

    • Atomic Spectroscopy, by W.C. Martin and W.L. Wiese in Atomic, Molecular, & Optical Physics Handbook, ed. by G.W.F. Drake (AIP, Woodbury, NY, 1996) Chapter 10, pp. 135–153. This website is also cited in the CRC Handbook as source of Section 1, subsection Electron Configuration of Neutral Atoms in the Ground State.
  • 91 Pa : [Rn] 5f2(3H4) 6d 7s2

  • 92 U : [Rn] 5f3(4Io9/2) 6d 7s2

  • 93 Np : [Rn] 5f4(5I4) 6d 7s2

  • 103 Lr : [Rn] 5f14 7s2 7p1 question-marked

  • 104 Rf : [Rn] 5f14 6d2 7s2 question-marked

CRC

  • David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition, online version. CRC Press. Boca Raton, Florida, 2003; Section 1, Basic Constants, Units, and Conversion Factors; Electron Configuration of Neutral Atoms in the Ground State. (elements 1–104)
  • Also subsection Periodic Table of the Elements, (elements 1–103) based on:
    • G. J. Leigh, Editor, Nomenclature of Inorganic Chemistry, Blackwell Scientific Publications, Oxford, 1990.
    • Chemical and Engineering News, 63(5), 27, 1985.
    • Atomic Weights of the Elements, 1999, Pure Appl. Chem., 73, 667, 2001.

WebElements

  • http://www.webelements.com/ ; retrieved July 2005, electron configurations based on:
    • Atomic, Molecular, & Optical Physics Handbook, Ed. Gordon W. F. Drake, American Institute of Physics, Woodbury, New York, 1996.
    • J.E. Huheey, E.A. Keiter, and R.L. Keiter in Inorganic Chemistry : Principles of Structure and Reactivity, 4th edition, Harper Collins, New York, 1993.
    • R.L. DeKock and H.B. Gray in Chemical Structure and bonding, Benjamin/Cummings, Menlo Park, California, 1980.
    • A.M. James and M.P. Lord in Macmillan's Chemical and Physical Data, Macmillan, London, UK, 1992.
  • 103 Lr : [Rn].5f14.7s2.7p1 tentative ; 2.8.18.32.32.9.2 [inconsistent]
  • 104 Rf : [Rn].5f14.6d2.7s2 tentative
  • 105 Db : [Rn].5f14.6d3.7s2 (a guess based upon that of tantalum) ; 2.8.18.32.32.11.2
  • 106 Sg : [Rn].5f14.6d4.7s2 (a guess based upon that of tungsten) ; 2.8.18.32.32.12.2
  • 107 Bh : [Rn].5f14.6d5.7s2 (a guess based upon that of rhenium) ; 2.8.18.32.32.13.2
  • 108 Hs : [Rn].5f14.6d6.7s2 (a guess based upon that of osmium) ; 2.8.18.32.32.14.2
  • 109 Mt : [Rn].5f14.6d7.7s2 (a guess based upon that of iridium) ; 2.8.18.32.32.15.2
  • 110 Ds : [Rn].5f14.6d9.7s1 (a guess based upon that of platinum) ; 2.8.18.32.32.17.1
  • 111 Rg : [Rn].5f14.6d10.7s1 (a guess based upon that of gold) ; 2.8.18.32.32.18.1
  • 112 Cn : [Rn].5f14.6d10.7s2 (a guess based upon that of mercury) ; 2.8.18.32.32.18.2
  • 113 Nh : [Rn].5f14.6d10.7s2.7p1 (a guess based upon that of thallium) ; 2.8.18.32.32.18.3
  • 114 Fl : [Rn].5f14.6d10.7s2.7p2 (a guess based upon that of lead) ; 2.8.18.32.32.18.4
  • 115 Mc : [Rn].5f14.6d10.7s2.7p3 (a guess based upon that of bismuth) ; 2.8.18.32.32.18.5
  • 116 Lv : [Rn].5f14.6d10.7s2.7p4 (a guess based upon that of polonium) ; 2.8.18.32.32.18.6
  • 117 Ts : [Rn].5f14.6d10.7s2.7p5 (a guess based upon that of astatine) ; 2.8.18.32.32.18.7
  • 118 Og : [Rn].5f14.6d10.7s2.7p6 (a guess based upon that of radon) ; 2.8.18.32.32.18.8

Lange

  • J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), online version, McGraw-Hill, 1999; Section 4, Table 4.1 Electronic Configuration and Properties of the Elements. (Elements 1–103)
  • 97 Bk : [Rn] 5f8 6d 7s2
  • 103 Lr : [Rn] 4f14 [sic] 6d 7s2

Hill and Petrucci

  • Hill and Petrucci, General Chemistry: An Integrated Approach (3rd edition), Prentice Hall. (Elements 1–106)
  • 58 Ce : [Xe] 4f2 6s2
  • 103 Lr : [Rn] 5f14 6d1 7s2

Hoffman, Lee, and Pershina

This book contains predicted electron configurations for the elements up to 172, as well as 184, based on relativistic Dirac–Fock calculations by B. Fricke in

References

  1. Jørgensen, Christian K.. (1988). "Handbook on the Physics and Chemistry of Rare Earths".
  2. (2006). "Electronic Configurations and the Periodic Table for Superheavy Elements". Pleaides Publishing.
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