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Calcium stearoyl-2-lactylate


| E482 | octadecanoic acid, 2-(1-carboxyethoxy)-1-methyl-2-oxoethyl ester, calcium salt | calcium bis(2-{[2-(stearoyloxy)propanoyl]oxy}propanoate) | calcium verate | calcium stearoyl lactylate | calcium stearoyl-2-lactylate | calcium stearyl-2-lactylate | calcium stelate | stearoyl-2-lactylic acid, calcium salt | calcium alpha-(alpha-(stearoyloxy)propionyloxy)propionate | calcium 2-(1-carboxyethoxy)-1-methyl-2-oxoethyloctadecanoate | stearic acid, ester with lactate of lactic acid, calcium salt | stearic acid ester with lactic acid bimol. ester calcium salt | calcium bis(2-(1-carboxylatoethoxy)-1-methyl-2-oxoethyl) distearate

Calcium stearoyl-2-lactylate (calcium stearoyl lactylate or CSL) or E482 is a versatile, FDA approved food additive. It is one type of a commercially available lactylate. CSL is non-toxic, biodegradable, and typically manufactured using biorenewable feedstocks. Because CSL is a safe and highly effective food additive, it is used in a wide variety of products from baked goods and desserts to packaging.

As described by the Food Chemicals Codex 7th edition, CSL is a cream-colored powder. CSL is currently manufactured by the esterification of stearic acid and lactic acid with partial neutralization using food-grade hydrated lime (calcium hydroxide). Commercial grade CSL is a mixture of calcium salts of stearoyl lactic acid, with minor proportions of other salts of related acids. The HLB for CSL is 5.1. It is slightly soluble in hot water. The pH of a 2% aqueous suspension is approximately 4.7.

Food labeling requirements

To be labeled as CSL for sale within the United States, the product must conform to the specifications detailed in 21 CFR 172.844. Tests for these specifications can be found in the Food Chemical Codex. Acceptance criteria for these two regions are as follows:

Specific TestAcceptance Criterion (FCC)Acceptance Criterion (EU)
Acid Value50 - 8650 - 130
Calcium Content4.2% - 5.2%1% - 5.2%
Ester Value125 - 164125 - 190
Total Recoverable Lactic Acid32.0% - 38.0%15% - 40%

To be labeled as CSL for sale in other regions, the product must conform to the specifications detailed in that region's codex.

Food applications and maximum use levels

CSL finds widespread application in baked goods, cereals, pastas, instant rice, desserts, icings, fillings, puddings, toppings, sugar confectionaries, powdered beverage mixes, creamers, cream liqueurs, dehydrated potatoes, snack dips, sauces, gravies, chewing gum, dietetic foods, minced and diced canned meats, and mostarda di frutta. In the United States, approved uses and use levels are described in 21 CFR 172.844, and 21 CFR 177.120. while the corresponding regulations in the EU are listed in Regulation (EC) No 95/2.

United StatesEuropean UnionApplicationMaximum use levelApplicationMaximum use levelApplicationMaximum use levelApplicationMaximum use level
Yeast-leavened bakery products0.5% of flourFine baked goods5 g/kgBread3 g/kgBreakfast cereals5 g/kg
Liquid and frozen egg whites0.05%Fat emulsions10 g/kgDesserts5 g/kgSugar confectionery5 g/kg
Dried egg whites0.5%Beverage whiteners3 g/kgHot powder beverage mixes2 g/lDietetic foods2 g/l
Whipped vegetable oil topping0.3%Quick-cook rice4 g/kgMinced and diced canned meats4 g/kgMostarda di frutta2 g/kg
Dehydrated potatoes0.5%Cereal-based snacks2 g/kgCereal- and potato-based snacks5 g/kgChewing gum2 g/kg
Paper and paperboard packaging componentNot limitedEmulsified liqueur8 g/lSpirits8 g/l
Cellophane0.5% weight of cellophane

The largest application of CSL is in yeast leavened bakery products. Although CSL was introduced to the market first, most applications use SSL. The main reason for the preference of SSL over CSL is that CSL has less crumb softening effects than SSL. However, CSL is still preferred in some applications, such as lean hearth bread-type formulations. In these applications, CSL is preferred because CSL performs better than SSL as a dough strengthener, while the finished product does not require a soft crumb or a perfectly symmetrical loaf shape.

References

References

  1. (1974). "Seventeenth Report of the Joint FAO/WHO Expert Committee on Food Additives, Who Food Additive Series 5".
  2. (2010). "A one-year oral toxicity study of sodium stearoyl lactylate (SSL) in rats". [[Food and Chemical Toxicology]].
  3. (2007). "Fatty Acids, C16-18 and C18-Unsaturated, Reaction Products with Lactic Acid and Monosodium Lactate (CAS# 847904-46-5): Ready Biodegradability by the Carbon Dioxide Evolution Test Method, Project No. 645E-101 for Caravan Ingredients". Wildlife International, Ltd..
  4. Markley, K.S.. (1960). "Fatty Acids Their Chemistry, Properties, Production, and Uses Part 1". Interscience Publishers, Inc..
  5. "Lactic Acid Production, Separation, and/or Recovery Process".
  6. (2004). "Handbook of Green Chemicals". Synapse Information Resources.
  7. (January 1, 2010). "Title 21 Code of Federal Regulations, part 172".
  8. (1995-03-18). "Regulation (EC) No 95/2 of the European Parliament and of the Council of 20 February 1995 on Food Additives Other Than Colours and Sweeteners". Official Journal of the European Union.
  9. (January 1, 2010). "Title 21 Code of Federal Regulations, part 172".
  10. "Food Chemical Codex".
  11. (1996-12-30). "Regulation (EC) No 96/77 of the European Parliament and of the Council of 2 December 1996 on Laying Down Specific Purity Criteria on Food Additives Other Than Colours and Sweeteners". Official Journal of the European Union.
  12. (January 1, 2010). "Title 21 Code of Federal Regulations, part 172".
  13. (2004). "Emulsifiers in Food Technology". Blackwell Publishing.
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This article was imported from Wikipedia and is available under the Creative Commons Attribution-ShareAlike 4.0 License. Content has been adapted to SurfDoc format. Original contributors can be found on the article history page.

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