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Bunsen cell

The Bunsen cell is a zinc-carbon primary cell (colloquially called a "battery") composed of a zinc anode in dilute sulfuric acid separated by a porous pot from a carbon cathode in nitric or chromic acid.

Cell details

The Bunsen cell generates about 1.9 volts which arises from the following reaction:

: Zn + H2SO4 + 2 HNO3 ZnSO4 + 2 H2O + 2 NO2(g)

According to the reaction above, when 1 mole (or part) each of zinc and sulfuric acid react with 2 moles (or parts) of nitric acid, the resultant products formed are, 1 mole (or part) of zinc sulfate and 2 moles (or parts) each of water and nitrogen dioxide (gaseous, in the form of bubbles).

The cell is named after its inventor, German chemist Robert Wilhelm Bunsen, who improved upon the Grove cell by replacing Grove's expensive platinum cathode with carbon in the form of pulverized coal and coke. Like Grove's battery, Bunsen's emitted noxious fumes of nitrogen dioxide.

Bunsen used this cell to extract metals. Henri Moissan used a stack of 90 cells for the electrolysis of hydrogen fluoride to obtain fluorine for the first time.

References

Carhart, Henry Smith. (1891). "Primary Batteries". Allyn and Bacon.

Wikipedia Source

This article was imported from Wikipedia and is available under the Creative Commons Attribution-ShareAlike 4.0 License. Content has been adapted to SurfDoc format. Original contributors can be found on the article history page.

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