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2-Aminothiophenol


Column 1Column 2
Preferred IUPAC name
2-Aminobenzene-1-thiol
Other names
CAS Number137-07-5 Y
3D model (JSmol)Interactive image
ChemSpider21111815
ECHA InfoCard100.004.798
EC Number205-277-3
PubChem CID8713
UNIIKIT82KOK2Z Y
CompTox Dashboard (EPA)DTXSID6051693
InChI
InChI=1S/C6H7NS/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2Key: VRVRGVPWCUEOGV-UHFFFAOYSA-NInChI=1/C6H7NS/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2Key: VRVRGVPWCUEOGV-UHFFFAOYAG
SMILES
c1ccc(c(c1)N)S
Chemical formulaC6H7NS
Molar mass125.19 g·mol−1
AppearanceColorless (impure samples are colored)
Density1.200 g/cm3
Melting point26 °C (79 °F; 299 K)
Boiling point234 °C (453 °F; 507 K)
Solubility in waterlow
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references | |

2-Aminothiophenol is an organosulfur compound with the formula C6H4(SH)(NH2). It is a colorless oily solid, although impure samples can be deeply colored. It is soluble in organic solvents and in basic water. 2-Aminothiophenol is a precursor to benzothiazoles, some of which are bioactive or are commercial dyes. Isomers of aminothiophenols include 3-aminothiophenol and 4-aminothiophenol.

2-Aminothiophenol can prepared in two steps, starting with the reaction of aniline with carbon disulfide followed by hydrolysis of the resulting mercaptobenzothiazole. It can also obtained by zinc reduction of 2-nitrobenzenesulfonyl chloride.

2-Aminothiophenol is used in the synthesis of the following list of agents:

  1. DDD-016
  2. BTM 1086
  3. Thioproperazine
  4. Cinanserin
  5. 1-Azaphenothiazine [261-96-1] (finds use in synthesis of Pipazethate, Prothipendyl, Cloxypendyl, Oxypendyl, & Isothipendyl).
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